A fridge plus a freezer should only use ~ 2-3 kwH per day unless you have a faulty thermostat in one of them - if you do then the compressors will run continuously and use a lot more power - have you checked that they are both switching correctly?
Also a fridge or freezer can use much more power if it hasn't been defrosted recently.
Was the water stone cold when you came home? If not have you got a back up immersion heater that has been left on?
However your usage still seems astronomical cf with average annual usage of ~ 65kWH per week - I live in a 5 bedroom detached house and we use a lot of gadgets ie computers,video recorders,TVs,stereo systems etc and have an electric oven and several fridges/freezers but we're only using ~130kWH per week on average this year including the cold Winter.
I presume you are quoting the usage from your monitor - does it agree with the actual meter?